ELECTRIC TRANSPORT IN MXENE-CHITOSAN NANOMEMBRANES
DOI:
https://doi.org/10.24867/25RB01DjericKeywords:
MXene, Polycaprolactone (PCL), Electrical conductivity, Two-dimensional nanomaterialsAbstract
This paper investigates the application of MXenes, two-dimensional (2D) nanomaterials, on polycaprolactone (PCL) membranes for food and medical technology purposes. MXenes are novel 2D materials consisting of layers of transition metal carbides, nitrides, or carbonitrides. PCL is a biocompatible, biodegradable polyester, suitable for medical applications. The electrical properties of PCL-MXene membranes were examined before and after oxygen plasma treatment. The results show an increase in conductivity after MXene deposition, which is not the case with plasma treatment. However, the treatment's influence on the electrical and mechanical properties of the nanocomposites was observed.
References
[1] Deshmukh, K., Basheer Ahamed, M., Deshmukh, R. R., Khadheer Pasha, S. K., Bhagat, P. R., & Chidambaram, K., „Biopolymer Composites With High Dielectric Performance: Interface Engineering,“ Biopolymer Composites in Electroniс, pp. 27-128, 2017. https://doi.org/10.1016/B978-0-12-809261-3.00003-6
[2] Hutmacher D. W., Schantz T., Zein I., Ng K. W., Teoh S. H. & Tan K. C., „Mechanical properties and cell cultural response of polycaprolactone scaffolds designed and fabricated via fused deposition modeling,“ Journal of Biomedical Materials Research, p. 203–216, 2001. https://doi.org/10.1002/1097-4636(200105)55:2<203::aid-jbm1007>3.0.co;2-7
[3] Lam C. X., Teoh S. H. & Hutmacher D. W.., „Comparison of the degradation of polycaprolactone and polycaprolactone–(β-tricalcium phosphate) scaffolds in alkaline medium,“ Polymer International, pp. 718-728, 2007. https://doi.org/10.1002/pi.2195
[4] Jenkins, M. J., & Harrison, K. L., „The effect of molecular weight on the crystallization kinetics of polycaprolactone“ Polymers for Advanced Technologies, p. 474–478. https://doi.org/doi:10.1002/pat.733
[5] Mondal, D., Griffith, M., & Venkatraman, S. S., „Polycaprolactone-based biomaterials for tissue engineering and drug delivery: Current scenario and challenges,“ . International Journal of Polymeric Materials and Polymeric Biomaterials, pp. 255-265, 2016. https://doi.org/10.1080/00914037.2015.1103241
[6] Sinha, V. R., Bansal, K., Kaushik, R., Kumria, R., & Trehan, A., „Poly-ϵ-caprolactone microspheres and nanospheres: an overview“ International Journal of Pharmaceutics, p. 1–23, 2004. https://doi.org/10.1016/j.ijpharm.2004.01.044
[7] Ikada, Y., & Tsuji, H., „Biodegradable polyesters for medical and ecological applications“ Macromolecular Rapid Communications, pp. 117-132, 2000. https://doi.org/10.1002/(sici)1521-3927(20000201)21:3<117::aid-marc117>3.0.co;2-x
[8] Naguib, M.; Kurtoglu, M.; Presser; V., Lu, J.; Niu, J.; Heon, M.; L., Hultman; Y, Gogotsi; Barsoum, M. W. „Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2“, Advanced Materials, pp. 4248-4253, 2011. https://doi.org/10.1002/adma.201102306
[9] B. &. G. Y. , Anasori, 2D Metal Carbides and Nitrides (MXenes), 2019.
[10] R. Garg, A. Agarwal и a. M. Agarwal1, „A review on MXene for energy storage application: effect of interlayer distance“ IOP Publishing, 2020. https://doi.org/10.1088/2053-1591/ab750d
[11] Eunji Lee, Armin VahidMohammadi, Barton C. Prorok, Young Soo Yoon, Majid Beidaghi, and Dong-Joo Kim, „Room Temperature Gas-Sensing of Two-Dimensional Titanium Carbide (MXene,“ Applied materials & interfaces, 2017 https://doi.org/10.1021/acsami.7b11055
[12] T. He, W. Liu, T. Lv, M. Ma, Z. Liu, A. Vasiliev и X. Li, „MXene/SnO2 heterojunction based chemical gas sensors,“ Sens. Actuators B Chem, 2021 https://doi.org/10.1016/j.snb.2020.129275
[13] Q. Li, Y. Li и a. W. Z. 1, „Preparation and Application of 2D MXene-Based Gas Sensors: A Review“ Chemosensors, pp. 1-40, 2021. https://doi.org/10.3390/chemosensors9080225
[2] Hutmacher D. W., Schantz T., Zein I., Ng K. W., Teoh S. H. & Tan K. C., „Mechanical properties and cell cultural response of polycaprolactone scaffolds designed and fabricated via fused deposition modeling,“ Journal of Biomedical Materials Research, p. 203–216, 2001. https://doi.org/10.1002/1097-4636(200105)55:2<203::aid-jbm1007>3.0.co;2-7
[3] Lam C. X., Teoh S. H. & Hutmacher D. W.., „Comparison of the degradation of polycaprolactone and polycaprolactone–(β-tricalcium phosphate) scaffolds in alkaline medium,“ Polymer International, pp. 718-728, 2007. https://doi.org/10.1002/pi.2195
[4] Jenkins, M. J., & Harrison, K. L., „The effect of molecular weight on the crystallization kinetics of polycaprolactone“ Polymers for Advanced Technologies, p. 474–478. https://doi.org/doi:10.1002/pat.733
[5] Mondal, D., Griffith, M., & Venkatraman, S. S., „Polycaprolactone-based biomaterials for tissue engineering and drug delivery: Current scenario and challenges,“ . International Journal of Polymeric Materials and Polymeric Biomaterials, pp. 255-265, 2016. https://doi.org/10.1080/00914037.2015.1103241
[6] Sinha, V. R., Bansal, K., Kaushik, R., Kumria, R., & Trehan, A., „Poly-ϵ-caprolactone microspheres and nanospheres: an overview“ International Journal of Pharmaceutics, p. 1–23, 2004. https://doi.org/10.1016/j.ijpharm.2004.01.044
[7] Ikada, Y., & Tsuji, H., „Biodegradable polyesters for medical and ecological applications“ Macromolecular Rapid Communications, pp. 117-132, 2000. https://doi.org/10.1002/(sici)1521-3927(20000201)21:3<117::aid-marc117>3.0.co;2-x
[8] Naguib, M.; Kurtoglu, M.; Presser; V., Lu, J.; Niu, J.; Heon, M.; L., Hultman; Y, Gogotsi; Barsoum, M. W. „Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2“, Advanced Materials, pp. 4248-4253, 2011. https://doi.org/10.1002/adma.201102306
[9] B. &. G. Y. , Anasori, 2D Metal Carbides and Nitrides (MXenes), 2019.
[10] R. Garg, A. Agarwal и a. M. Agarwal1, „A review on MXene for energy storage application: effect of interlayer distance“ IOP Publishing, 2020. https://doi.org/10.1088/2053-1591/ab750d
[11] Eunji Lee, Armin VahidMohammadi, Barton C. Prorok, Young Soo Yoon, Majid Beidaghi, and Dong-Joo Kim, „Room Temperature Gas-Sensing of Two-Dimensional Titanium Carbide (MXene,“ Applied materials & interfaces, 2017 https://doi.org/10.1021/acsami.7b11055
[12] T. He, W. Liu, T. Lv, M. Ma, Z. Liu, A. Vasiliev и X. Li, „MXene/SnO2 heterojunction based chemical gas sensors,“ Sens. Actuators B Chem, 2021 https://doi.org/10.1016/j.snb.2020.129275
[13] Q. Li, Y. Li и a. W. Z. 1, „Preparation and Application of 2D MXene-Based Gas Sensors: A Review“ Chemosensors, pp. 1-40, 2021. https://doi.org/10.3390/chemosensors9080225
Downloads
Published
2024-01-05
Issue
Section
Biomedical Engineering