DEGRADATION EFFICIENCY OF HETEROGENEOUS FENTON PROCESS IN THE TREATMENT OF MAGENTA FLEXO PRINTING DYE

Authors

  • Maja Kurdulija Autor
  • Vesna Kecić Autor
  • Miljana Prica FTN Autor

DOI:

https://doi.org/10.24867/02EF10Kurdulija

Keywords:

flexographic printing, Magenta, Fenton process, nano-zero valent iron, definitive screening design

Abstract

The aim of the master thesis is based on the flexographic printing field with the purpose to investigate the efficiency of Fenton process for treatment of Magenta flexographic dye, as well as to investigate the impact of various process conditions. Fenton process is very efficient in the degradation of various kinds of dyes. It is based on the addition of Fenton reagent, a mixture of hydrogen peroxide and iron ions, with the generation of hydroxyl radicals. Particles of nano-zero valent iron were used were used as a catalyst in Fenton process. The “green” synthesis of nanomaterial was carried out using fallen leaves of oak tree that grew in Fruška Gora National Park. Decolorization efficiency of printing dye aqueous solution was performed by series of experiments on the JAR test apparatus.

References

[1] J.J. Pignatello, E. Oliveros, A. Mackay, “Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry”, Critical Reviews in Environmental Science and Technology, Vol. 36, pp. 1-84, Januar 2006.

[2] Y.M. Liu, J. Xu, L. He, Y. Cao, H. He, D.Y. Zjao, J.H. Zhuang, K.N. Fan, “Facile Synthesis of Fe-Loaded Mesoporous Silica by a Combined Detemplation – Incorporation Process through Fenton’s Chemistry”, J. Phys. Chem., Vol. C112, pp. 16575-16583, Septembar 2008.

[3] H. Khalil, K. Tiangoua, M. Ghouti, “Synthesis of the mixed oxides of iron and quartz and their catalytic activities for the Fenton-like oxidation”, Catal. Commun., Vol. 9(5), pp. 955-959, Mart 2008.

[4] D. Tomašević, “Primena stabilizovanog nano nula valentnog gvožđa i komercijalnih imobilizacionih agenasa za remedijaciju sedimenta kontaminiranog metalima”, Doktorska disertacija, Prirodno–matematički fakultet, Univerzitet u Novom Sadu, Novi Sad, 2013.

[5] S. Machado, S. Pinto, J. Grosso, H. Nouws, J. Albergaria, C. Delerue–Matos, “Green production of zero–valent iron nanoparticles using tree leaf extracts”, Sci. Total Environ., Vol. 445–446, pp.1–8, Februar 2015.

[6] M. Fidaledo, R. Lavecchia, E. Petrucci, A. Zuorro, “Application of a novel definitive screening design to decolorization of an azo dye on boron–doped diamond electrodes” Int. J. Environ. Sci. Te., Vol. 13, pp. 835–842, Januar 2016.

[7] V. Kecić, Đ. Kerkez, M. Prica, O. Lužanin, M. Bečelić-Tomin, D. Tomašević Pilipović, B. Dalmacija, “Optimization of azo printing dye removal with oak leaves-nZVI/H2O2 system using statistically designed experiment”, J. Clean. Product., Vol. 202, pp. 65-80, Novembar 2018.

Published

2019-03-21